Viscoelastic Properties of Dilute Polymer Solutions(I)
نویسندگان
چکیده
منابع مشابه
Viscoelastic properties of polymer solutions.
In a concentrated polymer solution, the entanglement of long-chain molecules results in a transient network structure, to which may be attributed certain aspects of the viscoelastic behavior of such a system. A suitable mechanical model for representing this network as a first approximation is a retarded Maxwell element with one spring and two dashpots. Experimental measurements of mechanical p...
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The Rouse model has recently been modified to take into account the excluded volume interactions that exist between various parts of a polymer chain by incorporating a narrow Gaussian repulsive potential between pairs of beads on the Rouse chain (Prakash, 2000). The narrow Gaussian potential is characterized by two parameters: z∗ — which accounts for the strength of the interaction, and d∗ — wh...
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An oscillating capillary rheometer was used to investigate the dynamic viscoelastic and intrinsic viscosity properties of deacetylated xanthan (0.025%), native xanthan (0.025%), guar gum (0.075%), and xanthan–guar mixtures in dilute solutions. Influence of ionic strength on xanthan conformation and interaction with guar gum was elaborated. As the salt concentration increased, a significant (P <...
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A methodology for simple multiscale modeling of mechanical properties of polymer nanocomposites has been developed. This methodology consists of three steps: (1) obtaining from molecular dynamics simulations the viscoelastic properties of the bulklike polymer and approximating the position-dependent shear modulus of the interfacial polymer on the basis of the polymer-bead mean-square displaceme...
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The mixing of polymer matrices with nanoparticles to form composite materials has been an area of great research interest. The mechanical and rheological properties of such composite materials are directly related to the properties of the matrix polymer, the properties of the nano-filler, the strength and nature of the interfacial interactions between the polymer matrix and the filler, and fina...
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ژورنال
عنوان ژورنال: Kobunshi
سال: 1968
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.17.147